This is the Home Screen, when the user has logged there 4 goals, they get a percentage 100%, however atm when I log the 4 goals, 75% comes up and 3 out of 4 goals completed and 3 goals saved?
A very good way to learn App Inventor is to read the free Inventor's Manual here in the AI2 free online eBook App Inventor 2 Book: Create Your Own Android Apps ... the links are at the bottom of the Web page. The book 'teaches' users how to program with AI2 blocks.
There is a free programming course here Course In A Box and the aia files for the projects in the book are here: App Inventor 2 Book: Create Your Own Android Apps
How to do a lot of basic things with App Inventor are described here: How do you...? .
Try to understand what @Taifun say. You are error says, you are trying to pick 5th item of an 4 items array list. But there is no evidence in your block (using 5 in index place). In your screenshot the maxinum number used in index place is 4. So share us relevant blocks