Dear @Julio_Macias, first of all if you try to use the HC05 as a BLE, it will never work: the HC05 is a standard BT shield (provided it isn't a "fake" HC05 and it carries on it an AT-09 module instead. There is a very recent topic on the matter, look for it in the forum).
Assumed that your HC05 is a true one, therefore a standard BT, forget all about BLE.
On the opposite, whether you have a true BLE board to connect, there are really many examples on @Taifun's (puravidapps) , @ChrisWard's (professorcad) or @TIMAI2's (metricrat) web sites.
Moreover, as far as the simultaneous connection toward two different BT devices (one classic, i.e. an HC05 and one BLE, i.e. an HM-10) is concerned, the answer is yes, an AI2 app can connect such devices at the same time. A time ago I've developed an example to show how to connect two ESP32: the first via BLE and the second via classic BT. The ESP32 board features both BT's but I've use two of them because my aim was to see if a unique app could connect two different devices on two different BT standards.
You can find it here:
Hoping it helps.
All the best.